A FLUORINE-CONTAINING CRYPTAND FOR THE COMPLEXATION OF ANIONS AND THEUTILITY OF F-19 NMR-SPECTROSCOPY FOR THE DETERMINATION OF HOST GUEST ASSOCIATION

Authors
PLENIO H DIODONE R
Citation
H. Plenio et R. Diodone, A FLUORINE-CONTAINING CRYPTAND FOR THE COMPLEXATION OF ANIONS AND THEUTILITY OF F-19 NMR-SPECTROSCOPY FOR THE DETERMINATION OF HOST GUEST ASSOCIATION, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(7), 1995, pp. 1075-1078
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
7
Year of publication
1995
Pages
1075 - 1078
Database
ISI
SICI code
0932-0776(1995)50:7<1075:AFCFTC>2.0.ZU;2-H
Abstract
The first fluorine-containing cryptand F-3-TREN 4 for the complexation of anions was prepared in the 3+2-condensation reaction of 2-fluoro-1 ,3-phthalaldehyde 3 with tris(2-aminoethyl)amine and subsequent reduct ion with NaBH4. Upon incorporation of anionic guests 4 . 6HClO(4) expe riences shifts of its F-19 NMR resonances and thus demonstrates the ad vantages of studying host-guest association by F-19 NMR spectroscopy.