PALLADIUM-CATALYZED HYDROSILYLATION OF SILYL-SUBSTITUTED BUTADIENES

Authors
WENG WW CHEN RM LUH TY
Citation
Ww. Weng et al., PALLADIUM-CATALYZED HYDROSILYLATION OF SILYL-SUBSTITUTED BUTADIENES, Heteroatom chemistry, 6(1), 1995, pp. 15-18
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
6
Issue
1
Year of publication
1995
Pages
15 - 18
Database
ISI
SICI code
1042-7163(1995)6:1<15:PHOSB>2.0.ZU;2-R
Abstract
Palladium-catalyzed hydrosilylation of silyl-substituted butadienes 1 and 2 with MeSiCl(2)H has been investigated. Both steric effects and t he presence of an aryl substituent affect the regiochemistry of the hy drosilylation reaction. Hydrosilylation of siloxane-tethered bis-diene s 9 exhibits high regio- and diastereoselectivity.