,2-BIS(O-AMINOPHENOXY)ETHANE-N,N,N',N'-TETRAACETIC ACID-DERIVATIVES ON COMPLEXATION WITH LANTHANOID METAL-IONS - CORRELATION BETWEEN SIZE OF TRAPPING HOLE AND METAL-ION

Authors
KIMURA T ANDO T MARUYAMA T SUGIYAMA T OHNO A OKAMURA M
Citation
T. Kimura et al., ,2-BIS(O-AMINOPHENOXY)ETHANE-N,N,N',N'-TETRAACETIC ACID-DERIVATIVES ON COMPLEXATION WITH LANTHANOID METAL-IONS - CORRELATION BETWEEN SIZE OF TRAPPING HOLE AND METAL-ION, Heteroatom chemistry, 6(1), 1995, pp. 57-62
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
6
Issue
1
Year of publication
1995
Pages
57 - 62
Database
ISI
SICI code
1042-7163(1995)6:1<57:,AO>2.0.ZU;2-C
Abstract
Complexation of lanthanoid metal ions with 2-bis(o-aminophenoxy)-ethan e-N,N,N',N'-tetraacetic acid and its two derivatives, in which the dis tance between the chelating functions is changed, has been studied by potentiometric pH titration. There are two complexation modes dependin g on the size of the metal ion. Structural flexibility of the chelator accounts for the change in the complexation mode.