DERIVATIVE CHEMISTRY OF CATIONIC TRIRUTHENIUM CARBONYL CLUSTER COMPOUNDS - REACTIONS LEADING TO A NEUTRAL HEXANUCLEAR COMPLEX CONSISTING OF2 VERTEX-LINKED METAL TRIANGLES

Authors
CABEZA JA DELRIO I RIERA V GREPIONI F
Citation
Ja. Cabeza et al., DERIVATIVE CHEMISTRY OF CATIONIC TRIRUTHENIUM CARBONYL CLUSTER COMPOUNDS - REACTIONS LEADING TO A NEUTRAL HEXANUCLEAR COMPLEX CONSISTING OF2 VERTEX-LINKED METAL TRIANGLES, Organometallics, 14(7), 1995, pp. 3124-3126
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
7
Year of publication
1995
Pages
3124 - 3126
Database
ISI
SICI code
0276-7333(1995)14:7<3124:DCOCTC>2.0.ZU;2-U
Abstract
[Ru-6(mu(3)-ampy)(2)(CO)(18)] (1; Hampy = 2-amino-6-methylpyridine), t he first neutral hexanuclear carbonyl cluster complex consisting of tw o closed trimetal units connected by only one metal-metal bond (X-ray structure), has been prepared by (a) reaction of the cationic precurso r [Ru-3(mu(3)-ampy)(CO)(10)](+) (2) with aqueous NaOH, (b) reaction of complex 2 with the anion [Ru-3(mu(3)-ampy)(CO)(9)](-), and (c) zinc r eduction of complex 2.