COORDINATION PROPERTIES OF NOVEL TRIDENTATE CYCLOPENTADIENYL LIGANDS IN TITANIUM AND ZIRCONIUM COMPLEXES

Authors
DUPLOOY KE MOLL U WOCADLO S MASSA W OKUDA J
Citation
Ke. Duplooy et al., COORDINATION PROPERTIES OF NOVEL TRIDENTATE CYCLOPENTADIENYL LIGANDS IN TITANIUM AND ZIRCONIUM COMPLEXES, Organometallics, 14(7), 1995, pp. 3129-3131
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
7
Year of publication
1995
Pages
3129 - 3131
Database
ISI
SICI code
0276-7333(1995)14:7<3129:CPONTC>2.0.ZU;2-S
Abstract
Tridentate-linked amido-cyclopentadienyl ligands C(5)Me(4)SiMe(2)NCH(2 )R with a neutral donor site R (R = CH(2)OMe CH(2)NMe(2), CH=CH2) have been. synthesized and coordinated at tetravalent titanium and zirconi um centers. The molecular structure of Zr(eta(5):eta(1): eta(1)-C(5)Me (4)SiMe(2)NCH(2)CH(2)NMe(2))Cl-2 (4b) was determined by a single-cryst al X-ray structural analysis, revealing an unusual trigonal-bipyramida l zirconium center with the CH(2)CH(2)NMe(2) moiety interacting with t he zirconium center.