4-METHYL-1,4-THIABORIN, AN AROMATIC BORON-SULFUR HETEROCYCLE

Authors
ASHE AJ KAMPF JW WAAS JR
Citation
Aj. Ashe et al., 4-METHYL-1,4-THIABORIN, AN AROMATIC BORON-SULFUR HETEROCYCLE, Organometallics, 14(7), 1995, pp. 3141-3142
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
7
Year of publication
1995
Pages
3141 - 3142
Database
ISI
SICI code
0276-7333(1995)14:7<3141:4AABH>2.0.ZU;2-P
Abstract
The base-catalyzed hydrostannation of di-ethynyl sulfide with dibutyls tannane affords 4,4-dibutyl-1,4-thiastannin, which reacts with methylb oron dibromide to give 4-methyl-1,4-thiaborin. The thiaborin has been converted to arbonyl(eta(6)-4-methyl-1,4-thiaborin)-molybdenum, which has been characterized by single-crystal X-ray diffraction.