A STABLE PALLADIUM(I) DIMER WITH ONE 14E PALLADIUM CENTER AND ITS REVERSIBLE-REACTION WITH CS2, AFFORDING A NEW COMPLEX WITH A PLANAR 4-COORDINATE CARBON

Authors
LEONI P PASQUALI M PIERI G ALBINATI A PREGOSIN PS RUEGGER H
Citation
P. Leoni et al., A STABLE PALLADIUM(I) DIMER WITH ONE 14E PALLADIUM CENTER AND ITS REVERSIBLE-REACTION WITH CS2, AFFORDING A NEW COMPLEX WITH A PLANAR 4-COORDINATE CARBON, Organometallics, 14(7), 1995, pp. 3143-3145
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
7
Year of publication
1995
Pages
3143 - 3145
Database
ISI
SICI code
0276-7333(1995)14:7<3143:ASPDWO>2.0.ZU;2-B
Abstract
True new stable dinuclear Pd(I) complexes, [Pd-2(mu-PBu(t)2),(PPh(3))( 3)]X and [Pd-2(mu-PBu(2)(t))(PPh(3))(2)(mu,eta(2): eta(2)-CS2)]X(X = B F4, CF3SO3), have been synthesized and characterized. The former has o ne 14e Pd center, and the latter, which has been characterized by X-ra y diffraction, contains a CS2 molecule with a four-coordinate planar C S2 carbon.