A NEW CHIRAL TRIDENTATE FERROCENYL LIGAND - SYNTHESIS AND CHARACTERIZATION OF ITS PALLADIUM(II) AND NICKEL(II) COMPLEXES

Authors
BARBARO P TOGNI A
Citation
P. Barbaro et A. Togni, A NEW CHIRAL TRIDENTATE FERROCENYL LIGAND - SYNTHESIS AND CHARACTERIZATION OF ITS PALLADIUM(II) AND NICKEL(II) COMPLEXES, Organometallics, 14(7), 1995, pp. 3570-3573
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
7
Year of publication
1995
Pages
3570 - 3573
Database
ISI
SICI code
0276-7333(1995)14:7<3570:ANCTFL>2.0.ZU;2-7
Abstract
A novel chiral tridentate phosphine Ligand based on ferrocene (5) can be readily obtained fi om cyclohexylphosphine and -1-[(R)-2-(diphenylp hosphino)ferrocenyl]ethylamine (4) in acetic acid. Ligand 5 adopts a m eridional coordination geometry with d(8)-metal centers. The crystal s tructure of [Pd(S)CL]PF6 (6) has been determined.