UNUSUAL INTERACTION OF AG-ETHER - SYNTHESIS AND STRUCTURES OF [PDCL(L)] AND [PD(H2O)(L)(AG)][CF3SO3](2) (L=5,8,11-TRIOXA-2,14-DITHIA[15]-M-CYCLOPHANE)( WITH AN ORGANOPALLADIUM CROWN)

Authors
KICKHAM JE LOEB SJ
Citation
Je. Kickham et Sj. Loeb, UNUSUAL INTERACTION OF AG-ETHER - SYNTHESIS AND STRUCTURES OF [PDCL(L)] AND [PD(H2O)(L)(AG)][CF3SO3](2) (L=5,8,11-TRIOXA-2,14-DITHIA[15]-M-CYCLOPHANE)( WITH AN ORGANOPALLADIUM CROWN), Organometallics, 14(7), 1995, pp. 3584-3587
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
7
Year of publication
1995
Pages
3584 - 3587
Database
ISI
SICI code
0276-7333(1995)14:7<3584:UIOA-S>2.0.ZU;2-Z
Abstract
Reaction of 2 equiv of [Ag][CF3SO3] with the organopalladium crown eth er [PdCl(L)] (L = 5,8,11-trioxa-2,14-dithia[l5]-m-cyclophane) results in formation of AgCl and encapsulation of the second Ag+ ion to form t he bimetallic complex [Pd(H2O)(L)(Ag)][CF3SO3](2). The X-ray structure of [Pd(H2O)(L)(Ag)][CF3SO3]2 . CH2Cl2 shows that the electrophilic Ag + ion is bound to the Pd-C(aryl) unit and that this interaction is com plemented by peripheral coordination to the ether oxygens and a counte rion.