E. Lefebvre et al., RESULTS OF BROMIDE AND BROMATE MONITORING AT SEVERAL WATER-TREATMENT PLANTS, Ozone: science & engineering, 17(3), 1995, pp. 311-327
The ozonation of water is a widely used technology within the water in
dustry. Recent toxicological studies have shown that high bromate ion
intake induces a high incidence of tumors in rats. Bromate ion formati
on from oxidation of water containing bromide ion was examined at nine
treatment plants and one pilot. We found bromate ion (> 2 mu g/L) in
drinking water containing bromide ion when treated with ozone at pH gr
eater than 7.0, even in the presence of ammonia. Bromate ion formation
increased with the applied ozone dose. But bromate ion must be consid
ered also as a byproduct of commercial sodium hypochlorite solutions.
Under commercial conditions, chlorine dioxide and granular activated c
arbon had no effects on bromate levels.