K. Takahashi et S. Tarutani, NOVEL METALLIC CHARGE-TRANSFER COMPLEXES COMPOSED OF A [3]RADIALENE TYPE ACCEPTOR - A [2-(DICYANOMETHYLENE)-2,5-SELENOQUINO]CYCLOPROPANE DERIVATIVE, Advanced materials, 7(7), 1995, pp. 639-641
Communication: Molecular metals based on the [3]radialene structure (s
ee Fig.) as the acceptor are reported. They represent the first radial
ene and also the first non-benzenoid aromatic compounds to afford mole
cular metals, Compressed pellets of these accepters complexed with TTF
and TTT exhibit remarkable metallic behavior. The synthesis and the c
haracterization of the materials are presented.