SYNTHESIS AND CHARACTERIZATION OF DERIVATIVES OF COPPER(I) WITH N-DONOR LIGANDS .1. AZOLE AND BIS(AZOLYL)ALKANE COMPOUNDS - CRYSTAL-STRUCTURE OF NITRATO BIS(TRI-P-TOLYLPHOSPHINE)COPPER(I)
C. Pettinari et al., SYNTHESIS AND CHARACTERIZATION OF DERIVATIVES OF COPPER(I) WITH N-DONOR LIGANDS .1. AZOLE AND BIS(AZOLYL)ALKANE COMPOUNDS - CRYSTAL-STRUCTURE OF NITRATO BIS(TRI-P-TOLYLPHOSPHINE)COPPER(I), Polyhedron, 14(13-14), 1995, pp. 1709-1723
Several new complexes of the type [Cu(NO3)(PPh(3))(2)(L)(m)] (L = 3-me
thylpyrazole, 4-methylpyrazole, 3,5-dimethylpyrazole, 4-bromopyrazole
or bis(4-methylpyrazol-1-yl)methane, m = 1; L = pyrazole, 1,2,4-triazo
le or 2-methylimidazole, m = 2), [Cu(NO3)(PPh(3))(L)] (L = 3,4,5-trime
thylpyrazole or 4-phenylimidazole) [Cu(NO3) (PAr3)(n)(L)(3)] (Ar = p-
or m-tolyl, n = 0 or 1, L = pyrazole), [CuX(PPh(3))(2)(L)] (X = Cl, Br
or I, L = pyrazole or 3,5-dimethylpyrazole) and [CuX(PPh(3))(L)] (X =
Cl or Br, L = bis (pyrazol-1-yl)methane, bis(3,5-dimethylpyrazol-1-yl
) methane or bis(triazol-1-yl)methane) have been prepared and characte
rized by analytical and spectral data. The compounds [CuX(PPh(3))(2)(L
)] (X = Cl, Br or I, L = pyrazole or 3,5-dimethylpyrazole) are fluxion
al at temperature above 240 K. The dinuclear compound [Cu-2(PPh(3))(3)
(pzH)(2)] was obtained when the reaction between [CuI(PPh(3))(3)] and
pyrazole (pzH) was carried out in methanol containing alkali. In the c
rystal structure of the title compound, the copper atom is found in a
strongly distorted tetrahedral coordination [P-Cu-P: 128.0(1)degrees]
with two long Cu-O distances [2.217(9) and 2.184(9) Angstrom].