THE CRYSTAL-STRUCTURE OF (ASPH(4))(2)[RE(NO)(H2O)(CN)(4)]CENTER-DOT-5H(2)O

Authors
SMITH J PURCELL W LAMPRECHT GJ LEIPOLDT JG
Citation
J. Smith et al., THE CRYSTAL-STRUCTURE OF (ASPH(4))(2)[RE(NO)(H2O)(CN)(4)]CENTER-DOT-5H(2)O, Polyhedron, 14(13-14), 1995, pp. 1795-1797
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
13-14
Year of publication
1995
Pages
1795 - 1797
Database
ISI
SICI code
0277-5387(1995)14:13-14<1795:TCO(>2.0.ZU;2-B
Abstract
The crystal structure of (AsPh(4))(2)[Re(NO)(H2O)(CN)(4)]. 5H(2)O has been determined from three-dimensional X-ray diffraction data. The [Re (NO)(H2O)(CN)(4)](2-) ion has a distorted octahedral geometry with the following bond distances: Re-NO = 1.732(7), Re-OH2 = 2.165(5) and Re- CNav = 2.09 Angstrom. The NO group bond is at 178.4(7)degrees to the r henium atom and N-O = 1.181(8) Angstrom. The rhenium atom is displaced by 0.17 Angstrom out of the plane formed by the four carbon atoms of the cyano ligands towards the nitrosyl ligand.