THE CDCL2 THIAMINE (VITAMIN-B-1) SYSTEM - CRYSTAL-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF THE NEW COMPLEX TRANS-[CD(THIAMINE)(2)CL-4]/

Authors
CASAS JS CASTINEIRAS A COUCE MD SANCHEZ A SORDO J VARELA JM
Citation
Js. Casas et al., THE CDCL2 THIAMINE (VITAMIN-B-1) SYSTEM - CRYSTAL-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF THE NEW COMPLEX TRANS-[CD(THIAMINE)(2)CL-4]/, Polyhedron, 14(13-14), 1995, pp. 1825-1829
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
13-14
Year of publication
1995
Pages
1825 - 1829
Database
ISI
SICI code
0277-5387(1995)14:13-14<1825:TCT(S->2.0.ZU;2-1
Abstract
The structure of the title compound was determined by X-ray diffractio n. The cadmium atom is coordinated to the four chlorine ligands and to two N(1')-bound thiamines in S conformation that occupy a ans positio ns in a distorted octahedral kernel. The structural details and the so lid state (CP/MAS C-13 and Cd-113) and solution (C-13, N-15 and Cd-113 ) NMR spectroscopic properties of the complex are compared with those of previously isolated cadmium(II)/thiamine compounds.