ELECTROCHEMICAL, SPECTROELECTROCHEMICAL AND X-RAY-ABSORPTION SPECTROSCOPIC STUDY OF SOME IRON(II) AND IRON(III) POLYPYRAZOLYLBORATO COMPLEXES

Authors
ZAMPONI S GAMBINI G CONTI P LOBBIA GG MARASSI R BERRETTONI M CECCHI P
Citation
S. Zamponi et al., ELECTROCHEMICAL, SPECTROELECTROCHEMICAL AND X-RAY-ABSORPTION SPECTROSCOPIC STUDY OF SOME IRON(II) AND IRON(III) POLYPYRAZOLYLBORATO COMPLEXES, Polyhedron, 14(13-14), 1995, pp. 1929-1935
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
13-14
Year of publication
1995
Pages
1929 - 1935
Database
ISI
SICI code
0277-5387(1995)14:13-14<1929:ESAXS>2.0.ZU;2-1
Abstract
The electrochemical, UV-vis spectroelectrochemical and X-ray absorptio n spectroscopic characterization of some polypyrazolylborato complexes of iron(II) and iron(III) are reported. The UV-vis spectroelectrochem ical results have shown that changes in spin state occur during electr ochemical oxidation of some iron(II) complexes. The results of the UV- vis experiments have been correlated with the features of the X-ray ab sorption spectra recorded on the powdered compounds in the XANES regio n.