J. Ilic, ADVANTAGES OF PREFREEZING FOR REDUCING SHRINKAGE-RELATED DEGRADE IN EUCALYPTS - GENERAL-CONSIDERATIONS AND REVIEW OF THE LITERATURE, Wood Science and Technology, 29(4), 1995, pp. 277-285
Difficulties associated with the drying of ash eucalypts including col
lapse and internal checking, are discussed briefly. Prefreezing is one
method that has been used successfully as a pretreatment for the dryi
ng of both hardwoods and softwoods from temperate and tropical regions
. Prefreezing has produced marked reductions in shrinkage, collapse an
d drying degrade of the heartwood in the following species: California
redwood, black walnut, black cherry, tanoak, toon, bamboo, and eucaly
pts. Little or no collapse reduction has been observed in New Zealand
red beech, Pacific madrone, white birth, sitka spruce, and white ash.
Limited response has been observed for numerous other species notably
red oak and white oak. Reduced drying time in response to prefreezing
has been observed in jarrah, karri, black walnut, Asian oak, toon, and
California redwood; in Pacific madrone and tanoak the drying time inc
reased. Not all species which respond with a reduction in shrinkage sh
ow reduced drying rates. Prefreezing wood at -20 degrees C appears to
be the most practicable temperature, although some species respond bet
ter at lower temperatures. However, in all cases, it is critical to en
sure that the wood freezes and remains frozen for a number of hours. I
ndications are that the effect is retained for days to weeks and that
the length of time of freezing need not exceed 12-24 hours. A number o
f explanations have been put forward to explain the behaviour of prefr
ozen wood. It is suggested that the main mechanism responsible for red
uced shrinkage is due to the migration of moisture from the cell wall
onto frozen lumen water. The moisture loss from the cell wall produces
a 'cold shrinkage'; water to ice transformation leads to an expansion
of liquid water in the lumen, thus imparting a compressive stress to
the cell wall, which together with the moisture loss, make the cell mo
re rigid, and therefore likely to shrink less. There is some evidence
that certain types of wood extractives migrate into the cell wall duri
ng freezing and may play a role in the reinforcement of the wall. Redu
ced shrinkage after prefreezing has also been attributed to a reductio
n of the plasticising effect of wood extractives in wood dried at high
er temperatures and low humidities; this effect does not occur at low
temperatures.