SYNTHESIS OF HYDROXY-TERMINATED POLY(VINYL ETHERS) BY LIVING CATIONICPOLYMERIZATION .2. POLY(2-CHLOROETHYL VINYL ETHER) - A TELECHELIC POLYMER WITH REACTIVE PENDANTS

Authors
HASHIMOTO T AIZAWA H KODAIRA T
Citation
T. Hashimoto et al., SYNTHESIS OF HYDROXY-TERMINATED POLY(VINYL ETHERS) BY LIVING CATIONICPOLYMERIZATION .2. POLY(2-CHLOROETHYL VINYL ETHER) - A TELECHELIC POLYMER WITH REACTIVE PENDANTS, Macromolecular rapid communications, 16(7), 1995, pp. 521-526
Citations number
5
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular rapid communications → ACNP
ISSN journal
10221336
Volume
16
Issue
7
Year of publication
1995
Pages
521 - 526
Database
ISI
SICI code
1022-1336(1995)16:7<521:SOHPEB>2.0.ZU;2-C
Abstract
Hydroxy-terminated telechelic poly(2-chloroethyl vinyl ether) (poly(CE VE)) was synthesized by water-based end-capping reaction of living pol y(CEVE) with the initiating system CH3CHCl-OCH2CH2-OCOCH3/ZnCl2 in CH2 Cl2 at -40 degrees C and subsequent end-group transformation of the ac etate (alpha-end) and aldehyde (omega-end) groups into hydroxy groups. The obtained polymers possess controlled molecular weights and narrow molecular weight distributions.