GEOCHRONOLOGY AND GEOCHEMISTRY OF MULTIPLE GENERATIONS OF MONAZITE FROM THE WEPAWAUG SCHIST, CONNECTICUT, USA - IMPLICATIONS FOR MONAZITE STABILITY IN METAMORPHIC ROCKS
A. Lanzirotti et Gn. Hanson, GEOCHRONOLOGY AND GEOCHEMISTRY OF MULTIPLE GENERATIONS OF MONAZITE FROM THE WEPAWAUG SCHIST, CONNECTICUT, USA - IMPLICATIONS FOR MONAZITE STABILITY IN METAMORPHIC ROCKS, Contributions to Mineralogy and Petrology, 125(4), 1996, pp. 332-340
U-Pb isotope analyses, rare earth and trace element analyses, and petr
ographic observations are presented for monazites from the Wepawaug Sc
hist in southern Connecticut, USA. Two samples of kyanite zone schist
were collected less than a meter apart. Each sample contains a differe
nt variety of monazite with distinct morphology, chemistry, and Pb iso
topic composition. One sample preserves a largely amphibolite facies m
ineralogy, including kyanite, staurolite, garnet, biotite, and chlorit
e, with little textural evidence of later shearing. Monazites from thi
s sample are xenoblastic with about 1 wt% ThO2, 0.3 wt% CaO, and a mor
e LREE enriched pattern than monazites from the second sample. These x
enoblastic monazites preserve textural evidence of a retrograde reacti
on to apatite which involves chlorite, indicating that these monazites
became unstable during retrograde chloritization of biotite. These mo
nazites give strongly discordant U-Pb ages which fit a chord with an u
pper intercept age of 411 +/- 18 Ma, interpreted as the minimum growth
age of these xenoblastic monazites, perhaps during amphibolite facies
metamorphism. The second sample contains S-C banding, evidence of dyn
amic recrystallization, and abundant retrograde chlorite. This sample
contains idioblastic monazites with about 3 wt% ThO2, 0.8 wt% CaO, and
with less fractionated REE patterns. These monazites give close to co
ncordant U-Pb ages with a mean Pb-207/Pb-206* age of 388 +/- 2 Ma. Th
is age is interpreted as probably representing the time of retrogressi
on of the sample from an amphibolite to greenschist facies mineralogy.