M. Takabatake et al., INDIUM TIN OXIDE DRY-ETCHING USING HBR GAS FOR THIN-FILM-TRANSISTOR LIQUID-CRYSTAL DISPLAYS, Journal of the Electrochemical Society, 142(7), 1995, pp. 2470-2473
The dry etching technique for indium tin oxide (ITO) films has been in
vestigated using HBr gas with a conventional parallel-plate-type react
ive ion etching apparatus in order to fabricate ITO fine patterns for
thin-film transistor addressed liquid crystal displays (TFT-LCDs). Etc
hing rates of amorphous ITO and poly-ITO were almost the same, unlike
the case with ITO wet etching. This demonstrates that the ITO etching
rate using HBr gas is independent of the film characteristics. A scann
ing electron microscopy study of etched ITO films showed that the reac
tion products were not deposited on the sample surface, although the r
esist surface was roughened. Al films, which are the underlayers of IT
O films for TFT-LCDs, were not etched by HBr gas only. Therefore, high
ITO/Al selectivity can be obtained by HBr gas.