SYNTHESIS OF ONIO-SUBSTITUTED, DIONIO-SUBSTITUTED, AND TRIONIO-SUBSTITUTED PHOSPHINES - THE NUCLEOPHILIC BEHAVIOR OF DBN AND DBU TOWARD MAIN-GROUP ELECTROPHILES

Authors
BOUHADIR G REED RW REAU R BERTRAND G
Citation
G. Bouhadir et al., SYNTHESIS OF ONIO-SUBSTITUTED, DIONIO-SUBSTITUTED, AND TRIONIO-SUBSTITUTED PHOSPHINES - THE NUCLEOPHILIC BEHAVIOR OF DBN AND DBU TOWARD MAIN-GROUP ELECTROPHILES, Heteroatom chemistry, 6(4), 1995, pp. 371-375
Citations number
36
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
6
Issue
4
Year of publication
1995
Pages
371 - 375
Database
ISI
SICI code
1042-7163(1995)6:4<371:SOODAT>2.0.ZU;2-J
Abstract
1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) and 1,8-diazabicyclo[5.4.0]unde c-7-ene (DBU) react with chloro- and dichloro-phosphines leading to on io- and dionio-substituted phosphines. Similarly, onio-substituted sil icon and tin derivatives are prepared; they are used as onio-substitue nt transfer reagents in the synthesis of a trionio-substituted phosphi ne.