Ki. Gnanasekar et al., STRUCTURAL STABILITY OF LUBA2CU3O7-DELTA AND SUPERCONDUCTIVITY IN THIN-FILMS OF LU(1-X)M(X)BA(2)CU(3)O(7-DELTA) (M=PR, TB, AND CE), Physical review. B, Condensed matter, 52(2), 1995, pp. 1362-1367
We present here the results of our investigations of the structural an
d superconducting properties of thin films of Lu(1-x)M(x)Ba(2)Cu(3)O(7
-delta) (M=Ce, Pr, and Tb), the three ambivalent rare-earth ions. Our
results show that Pr and Tb ions are in the trivalent state and Ce ion
s are tetravalent. Structural (in)stability of the parent material LuB
a2Cu3O7-delta forms the basis of our arguments. We suggest a simple mo
del to account for the influence of Pr ions on superconductivity in cu
prates.