SYNTHESIS AND CRYSTAL-STRUCTURE OF BAPD2S4 - A SULFIDE-DISULFIDE COMPOUND, BAPD2S2(S-2)

Authors
HUSTER J BRONGER W
Citation
J. Huster et W. Bronger, SYNTHESIS AND CRYSTAL-STRUCTURE OF BAPD2S4 - A SULFIDE-DISULFIDE COMPOUND, BAPD2S2(S-2), Journal of alloys and compounds, 224(2), 1995, pp. 190-193
Citations number
9
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
224
Issue
2
Year of publication
1995
Pages
190 - 193
Database
ISI
SICI code
0925-8388(1995)224:2<190:SACOB->2.0.ZU;2-L
Abstract
Single crystals of BaPd2S4 have been grown in an H2S-stream from a mix ture of BaPd(CN)(4) . 4H(2)O acid BaS in a KSCN-melt. The crystal stru cture was solved using single crystal X-ray diffraction methods. BaPd2 S4 is monoclinic, P2(1)/m, a=7.252(1) Angstrom, b=6.764(1) Angstrom, c =6.687(1) Angstrom, beta=110.45(1)degrees, Z=2. The new structure type contains sulphur-palladium-sulphur layers in which two crystallograph ic-different palladium (II) ions are planar coordinated by sulphide an d disulphide ions. The layers are connected by barium ions.