REACTION OF TRICARBONYL(ETA(6)-CYCLOHEPTATRIENYL)MANGANESE WITH ZINC-COPPER COUPLING REAGENTS

Citation
Yk. Yun et Kf. Mcdaniel, REACTION OF TRICARBONYL(ETA(6)-CYCLOHEPTATRIENYL)MANGANESE WITH ZINC-COPPER COUPLING REAGENTS, Tetrahedron letters, 36(28), 1995, pp. 4931-4934
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
28
Year of publication
1995
Pages
4931 - 4934
Database
ISI
SICI code
0040-4039(1995)36:28<4931:ROTWZ>2.0.ZU;2-G
Abstract
Reaction of zinc-copper coupling reagents with tricarbonyl(eta 6-cyclo heptatrienyl)manganese hexafluorophosphate provides (6-exo-substituted -eta 5-cycloheptadienyl)manganese complexes in 48-78% yield. Attempts to alkylate tricarbonyl(eta 6-benzene)manganese cations under similar reactions conditions failed.