CHARACTERISTICS OF CATALYST FOR CARBON-MONOXIDE COUPLING REACTION

Citation
Gh. Xu et al., CHARACTERISTICS OF CATALYST FOR CARBON-MONOXIDE COUPLING REACTION, Industrial & engineering chemistry research, 34(7), 1995, pp. 2379-2382
Citations number
6
Categorie Soggetti
Engineering, Chemical
ISSN journal
08885885
Volume
34
Issue
7
Year of publication
1995
Pages
2379 - 2382
Database
ISI
SICI code
0888-5885(1995)34:7<2379:COCFCC>2.0.ZU;2-X
Abstract
The carbon monoxide coupling reaction on supported metal catalysts Pd/ Al2O3 and Pd-Fe/Al2O3 was used to study the characteristics of the cat alyst under different conditions. The results indicated that the catal ytic activation temperature influenced the catalytic activity and that there was an optimum activation temperature. The characteristics of e ffective coupling catalysts were found to be smaller surface areas and bigger pores, for example the alpha-phase of aluminum oxide. X-ray ph otoelectron spectroscopic analysis results show that the catalytic rea ction of CO coupling occurs via a redox mechanism.