STRUCTURE OF METHYLSILYL-BIS(ETA(5)-CYCLOPENTADIENYL)TITANA(IV) CYCLOHEXASULFANE, TI[ME(2)SI(ETA(5)-C5H4)(2)]S-5

Authors
RAPTOPOULOU CP TERZIS A TZAVELLAS N KLOURAS N
Citation
Cp. Raptopoulou et al., STRUCTURE OF METHYLSILYL-BIS(ETA(5)-CYCLOPENTADIENYL)TITANA(IV) CYCLOHEXASULFANE, TI[ME(2)SI(ETA(5)-C5H4)(2)]S-5, Zeitschrift fur anorganische und allgemeine Chemie, 621(7), 1995, pp. 1257-1260
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
7
Year of publication
1995
Pages
1257 - 1260
Database
ISI
SICI code
0044-2313(1995)621:7<1257:SOMC>2.0.ZU;2-8
Abstract
The X-ray crystal structure of Ti[Me(2)Si(eta(5)-C5H4)(2)]S-5 has been determined. The coordination about the titanium may be described as a distorted tetrahedron. The (centroid)-Ti-(centroid) angle is 129.2 de grees and the S-Ti-S bond angle 96.1 degrees. The cyclopentadienyl rin gs are linked by a dimethylsilyl bridge. The sixmembered ring TiS5 has a cyclohexane-like chair configuration. The four S-S distances range from 2.048 to 2.059 Angstrom. Important structural dimensions are comp ared to those of similar type compounds.