A NEW LITHIUM HYDROGEN SULFATE, LI-2(HSO4 )(2)(H2SO4) - SYNTHESIS ANDCRYSTAL-STRUCTURE

Authors
WERNER C KEMNITZ E TROYANOV S STRUTSCHKOV YT WORZALA H
Citation
C. Werner et al., A NEW LITHIUM HYDROGEN SULFATE, LI-2(HSO4 )(2)(H2SO4) - SYNTHESIS ANDCRYSTAL-STRUCTURE, Zeitschrift fur anorganische und allgemeine Chemie, 621(7), 1995, pp. 1266-1269
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
7
Year of publication
1995
Pages
1266 - 1269
Database
ISI
SICI code
0044-2313(1995)621:7<1266:ANLHSL>2.0.ZU;2-X
Abstract
The title compound crystallizes in good shaped single crystals from th e system lithium sulfate/sulfuric acid in the orthorhombic space group Peen, unit cell parameters a = 17.645(4), b = 5.378(1), c = 10.667(3) Angstrom. V = 1012.2 Angstrom(3), Z = 4, D-x = 2.009 g cm(-3). There are two types of SO4 tetrahedra, SO3(OH) and SO2(OH)(2), connected via hydrogen bonds forming layers parallel to the xy-plane. The layers ar e linked by Li atoms, which are tetrahedral coordinated by O atoms com ing two by two from neighboured layers.