LIGAND-EXCHANGE REACTIONS OF BIS(ACETYLAC ETONATO)DIOXO-MOLYBDENNM(VI) - CRYSTAL-STRUCTURES OF NZOYLHYDRAZONATO(2-)]DIOXO-METHANOL-MOLYBDENUM(VI) AND O(2-)]DIOXO-TRIPHENYLPHOSPHANEOXIDE-MOLYBDENUM(VI)

Authors
BANSSE W LUDWIG E SCHILDE U UHLEMANN E WELLER F LEHMANN A
Citation
W. Bansse et al., LIGAND-EXCHANGE REACTIONS OF BIS(ACETYLAC ETONATO)DIOXO-MOLYBDENNM(VI) - CRYSTAL-STRUCTURES OF NZOYLHYDRAZONATO(2-)]DIOXO-METHANOL-MOLYBDENUM(VI) AND O(2-)]DIOXO-TRIPHENYLPHOSPHANEOXIDE-MOLYBDENUM(VI), Zeitschrift fur anorganische und allgemeine Chemie, 621(7), 1995, pp. 1275-1281
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
7
Year of publication
1995
Pages
1275 - 1281
Database
ISI
SICI code
0044-2313(1995)621:7<1275:LROBE>2.0.ZU;2-G
Abstract
The products of ligand exchange reactions between bis(acetylacetonato) dioxo-molybdenum(VI) and tridentate diacidic ligands H(2)L in the pres ence of triphenylphosphane were found by mass spectrometry to be compl exes of the type MoO(2)L. In the case of salicylaldehyde 2-hydroxyanil MoL(2) could also be identified. The compounds MoO(2)L were crystalli zed as complexes with methanol or triphenylphosphane oxide. Crystallog raphic data see ''Inhaltsubersicht''.