The morphology of bismuth layers on Si(001) has been investigated by e
lectron spectroscopy methods (AES, EELS) and thermodesorption mass-spe
ctrometry. Island formation on the first Bi continuous monolayer occur
s during bismuth deposition at room temperature. The thermodesorption
of this system at a temperature of similar to 500 degrees C leads to t
he formation of at least one stable adsorbed Bi phase with a coverage
of similar to 0.6-0.7 ML. Bi O-4.5-line REELS of the Bi/Si(001) system
has demonstrated the covalent character of the Bi-Si bond.