We investigated the morphological and structural changes that occur du
ring the growth of Cu on Si(111)(7 x 7) at different substrate tempera
tures using reflection high energy electron diffraction (RHEED). For t
emperatures up to 100 degrees C Cu grows in a layer-by-layer like fash
ion as indicated by the observation of RHEED intensity oscillations. T
he interface is intermixed, but only for growth above -50 degrees C we
found evidence for the formation of eta-Cu3Si. Above 150 degrees C th
e oscillations disappear and the growth proceeds in the Stranski-Krast
anov mode producing a very rough surface.