We present a detailed investigation of the Na/InAs(110) interface form
ation at room temperature by synchrotron radiation core-level photoemi
ssion spectroscopy. At very low Na coverages only one type of adsorpti
on site is observed. This stage corresponds to a large downward band b
ending for both n- and p-type samples, which leads to a Ferrni-level p
inning position well above the conduction band minimum. With further N
a deposition a second Na 2p component appears; this is accompanied by
a decrease of the band bending. At high coverages one observes a very
strong chemical reaction between the substrate and Na. This interface
formation is compared with our previous study of the Cs/InAs(110) syst
em.