H. Jancke et al., STRUCTURE OF SUBSTITUTED AMINOMETHANEBISPHOSPHONIC ACIDS ANALYZED BY NMR-SPECTROSCOPY AND X-RAY-POWDER DIFFRACTION, Fresenius' journal of analytical chemistry, 352(5), 1995, pp. 496-498
The P-31 NMR spectra of a series of substituted aminomethanebisphospho
nic acids (AMBAs) are reported. The AMBAs may crystallize as anhydrate
s or in hydrated form. The appearance of more than one P-31 NMR signal
in the solid state NMR spectra of AMBAs is an indication for a comple
x molecular order with non-equivalent phosphorus sites.