Field and greenhouse studies were performed to examine the influence o
f various surfactants with glyphosate on whole plant efficacy. Relatio
nships were examined between glyphosate phytotoxicity and surfactant p
roperties, including ionic form, degree of ethoxylation, and hydrophob
e composition. Cationic tertiary amine surfactants enhanced glyphosate
performance in both field and greenhouse studies. Nonionic allinol an
d octoxynol surfactants were not effective in combination with glyphos
ate. In field studies, glyphosate efficacy increased with increasing s
urfactant ethylene oxide (EO) content. Soybean and velvetleaf responde
d similarly to glyphosate-surfactant spray applications, as both demon
strated significant linear and quadratic relationships between increas
ing surfactant ethoxylation and phytotoxicity, while common lambsquart
ers showed a significant linear relationship only, Cationic surfactant
s were evaluated in the greenhouse and a significant quadratic regress
ion of glyphosate phytotoxicity to common lambsquarters on increasing
surfactant ethoxylation indicated an optimum surfactant EO content of
about 10 moles, Both tertiary and quaternary ethoxylated fatty amines
were effective with glyphosate in decreasing common lambsquarters' fre
sh weight, Fatty amine hydrophobe composition did not correlate with g
lyphosate phytotoxicity to common lambsquarters. Nomenclature: Glyphos
ate, N-(phosphonomethyl)glycine; common lambsquarters, Chenopodium alb
um L. #(3) CHEAL; velvetleaf, Abutilon theophrasti Medicus # ABUTH; so
ybean, Glycine max (L.) Merr. 'Elgin.'