B. Boubeker et al., A MOSSBAUER STUDY OF BCE STAINLESS-STEEL FILMS, Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 101(3), 1995, pp. 267-274
Conversion electron Mossbauer spectroscopy is used to investigate the
ferromagnetic state of bcc stainless steel films. First, a low tempera
ture study allows the resolution of the local Fe environments. It is f
ound that the main environments correspond to three Fe sites with diff
erent short-range order. Second, a phase transition takes place at tem
peratures higher than 750 K. Evidence is found that, during an isother
mal kinetic at 913 K, the ferromagnetic part of the Mossbauer spectra
splits up into two components, thus indicating the existence of two fe
rromagnetic iron sites. The index n and activation energy Q in the Joh
nson-Mehl-Avrami plot are found to be 0.53-0.68 and 366-462 kJ mol(-1)
, respectively. The role of Cr atoms is also discussed.