REACTION OF ORGANOHALOGENS WITH IN-SITU ELECTROGENERATED SUPEROXIDE ION

Authors
DWIVEDI S SINGH M MISRA RA
Citation
S. Dwivedi et al., REACTION OF ORGANOHALOGENS WITH IN-SITU ELECTROGENERATED SUPEROXIDE ION, Journal of the Indian Chemical Society, 72(1), 1995, pp. 37-39
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Indian Chemical Society → ACNP
ISSN journal
00194522
Volume
72
Issue
1
Year of publication
1995
Pages
37 - 39
Database
ISI
SICI code
0019-4522(1995)72:1<37:ROOWIE>2.0.ZU;2-2
Abstract
Superoxide ion, generated by electrochemical reduction of O-2 in dimet hylformamide at mercury cathode, reacts as an effective nucleophile wi th hloareness (1a-4a) and as a base with phenacyl halides (5a and 6a) affording phenols (1a-4b) and trans-dibenzoylethene (5b) respectively.