W. Chen et al., INVESTIGATION ON THE ORIGIN OF THE BLUE EMISSION IN TITANIUM-DOPED SAPPHIRE - IS F-CENTER THE BLUE EMISSION CENTER( COLOR), Applied physics letters, 67(3), 1995, pp. 317-319
Titanium doped sapphire (Ti:Al2O3) shows a 420 nm blue emission band w
hose corresponding excitation band lies at 244 nm. With the aim of asc
ertaining the origin of this blue emission, using synchrotron radiatio
n we measured the vacuum ultraviolet to ultraviolet absorption spectru
m of titanium doped sapphire. It is suggested that the blue emission i
s due to a center other than a trivalent Ti3+ ion or a tetravalent Ti4
+ ion, most probably an F+-type color center formed in the crystal. (C
) 1995 American Institute of Physics.