The third-order optical nonlinearity ((3)(chi)) of porous silicon has
been measured using the Z-scan technique. Intensity dependent absorpti
on was observed and attributed to a resonant two photon absorption pro
cess. The real and imaginary parts of ((3)(chi)) have been measured at
665 nm and found to be 7.5x10(-9) esu and -1.9x10(-9) esu, respective
ly. This constitutes a significant esu enhancement over crystalline si
licon, All optical switching based on nonlinear absorption is demonstr
ated. (C) 1995 American Institute of Physics.