The crystalline structure of GaN epilayers on (0001) SiC substrates ha
s been studied using x-ray diffraction and transmission microscopy. Th
e films were grown by metalorganic chemical vapor deposition, using A1
N buffer layers. X-ray diffraction measurements show negligible strain
in the epilayer, and a long-range variation in orientation. Transmiss
ion electron lattice images show that the ALN buffer layer consists of
small crystallites. The nature of the buffer layer and its interfaces
with the substrate and the GaN film is discussed. The defect structur
e of the GaN film away from the substrate consists mostly of threading
dislocations with a density of similar to 10(9) cm(-2). (C) 1995 Amer
ican Institute of Physics.