ELECTROLYTIC REDUCTION OF LEAD IONS IN HALIDE MELTS

Authors
YURKINSKII VP MAKAROV DV
Citation
Vp. Yurkinskii et Dv. Makarov, ELECTROLYTIC REDUCTION OF LEAD IONS IN HALIDE MELTS, Russian journal of applied chemistry, 67(8), 1994, pp. 1132-1135
Citations number
12
Categorie Soggetti
Chemistry Applied
Journal title
Russian journal of applied chemistry → ACNP
ISSN journal
10704272
Volume
67
Issue
8
Year of publication
1994
Part
1
Pages
1132 - 1135
Database
ISI
SICI code
1070-4272(1994)67:8<1132:EROLII>2.0.ZU;2-N
Abstract
The kinetics of Pb(II) reduction in chloride-bromide melts has been st udied in the 670-780 K range by means of linear voltammetry, chronopot entiometry, and chronoamperometry. It was found that an electrode proc ess in an LiCl-KCl chloride melt is controlled by lead ion diffusion. In chloride-bromide melts the process is complicated by the preceding stage of the dissociation of lead complex ions.