KINETIC RESULTS OF THE BASIC DISULFURE BOND SCISSION OF 5,5'-DITHIOBIS(2-NITROBENZOIC) ACID AND 6,6'-DITHIODINICOTINIC ACID IN CTAB MICELLES ANALYZED ON THE BASE OF POISSON-BOLTZMANN EQUATION

Authors
RODENAS E DOLCET C VALIENTE M SIERRA ML REINA P
Citation
E. Rodenas et al., KINETIC RESULTS OF THE BASIC DISULFURE BOND SCISSION OF 5,5'-DITHIOBIS(2-NITROBENZOIC) ACID AND 6,6'-DITHIODINICOTINIC ACID IN CTAB MICELLES ANALYZED ON THE BASE OF POISSON-BOLTZMANN EQUATION, Journal de chimie physique et de physico-chimie biologique, 92(6), 1995, pp. 1205-1213
Citations number
7
Categorie Soggetti
Biology,"Chemistry Physical
Journal title
Journal de chimie physique et de physico-chimie biologique → ACNP
Volume
92
Issue
6
Year of publication
1995
Pages
1205 - 1213
Database
ISI
SICI code
Abstract
The basic disulfure bond scission of 5,5'-dithiobis(2-nitrobenzoic) ac id and 6,6'-dithiodinicotinic acid has been studied on CTAB micelles, The kinetic results are explained well on the base of theoretical trea tment that considers ions distribution around micelles according to th e Poisson-Boltzmann mon-linearized equation with specific interactions between ions in solution and the micellar surface. The treatment also considers ionic substrate distribution between aqueous and micellar p hases that depends on the micellar surface potential.