M. Broquier et al., FREE-ELECTRON LASER AS A TOOL FOR PUMP-PROBE MEASUREMENTS OF THE VIBRATIONAL-RELAXATION IN CONDENSED PHASES, Optics communications, 118(3-4), 1995, pp. 255-260
In this communication, we discuss the interest of the infrared free-el
ectron laser (CLIO) for measurements of vibrational relaxation rates a
t the picosecond scale by a one-color pump-probe experiment. We report
the results of preliminary experiments involving small molecules (CO,
CO2) in low-temperature argon matrices and intermediate-size molecule
s (acetonitrile, ben zonitrile) in room-temperature CCl4 solutions.