THERMOLYSIS, PHOTOLYSIS, AND OXIDATION OF AN OVERCROWDED 1,3,2-DITHIASTANNETANE DERIVATIVE

Authors
TOKITOH N STRESING V MATSUHASHI Y OKAZAKI R
Citation
N. Tokitoh et al., THERMOLYSIS, PHOTOLYSIS, AND OXIDATION OF AN OVERCROWDED 1,3,2-DITHIASTANNETANE DERIVATIVE, Heteroatom chemistry, 6(2), 1995, pp. 155-160
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
6
Issue
2
Year of publication
1995
Pages
155 - 160
Database
ISI
SICI code
1042-7163(1995)6:2<155:TPAOOA>2.0.ZU;2-8
Abstract
Reactions of a sterically crowded 1,3,2-dithiastannetane derivative be aring 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (=Tbt) and 2,4,6-tri isopropylphenyl (=Tip) groups on the tilt atom are described. Both the rmolysis and photolysis of the 1,3,2,-dithiastannetane [Tbt(Tip)SnS(2) CPh(2)] resulted in the formation of products derived from the corresp onding stannanethione [Tbt(Tip)Sn=S], while the oxidation reaction by m-chloroperbenzoic acid gave a novel tin-containing heterocyclic syste m, an 1,2,4,5-oxadithiastannolane derivative.