Cm. Raj et Cp. Prabhakaran, SYNTHESIS AND CHARACTERIZATION OF SOME MULTIDENTATE LIGAND COMPLEXES OF MN(III) THIOCYANATE AND SELENOCYANATE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(8), 1995, pp. 652-654
N,N'-(Ethylene)bis(salicylideneimine) (EDSAL), N,N'-(propylene)bis(sal
icyclideneimine) (PDSAL) and N,N'-(o-phenylene)bis(salicyclideneimine)
(o-PhenSAL) complexes of Mn(III) selenocyanate and 1,2-dihydro-1,5-di
methyl-2-phenyl- 4-(2'-hydroxynaphthylazo-)3H-pyrazol-3-one (NAAP) com
plexes of Mn(III) thiocyanate and selenocyanate of the formulae MnL(NC
Se) (L = EDSAL, PDSAL or o-PhenSAL) and MnL(NCX)(2) (L = NAAP and X =
S or Se) have been isolated and characterized. All the complexes are n
on-electrolytic in nature. The IR spectra of these complexes are indic
ative of coordination through nitrogen atom of the NCX group.