SYNTHESIS AND CHARACTERIZATION OF SOME MULTIDENTATE LIGAND COMPLEXES OF MN(III) THIOCYANATE AND SELENOCYANATE

Authors
RAJ CM PRABHAKARAN CP
Citation
Cm. Raj et Cp. Prabhakaran, SYNTHESIS AND CHARACTERIZATION OF SOME MULTIDENTATE LIGAND COMPLEXES OF MN(III) THIOCYANATE AND SELENOCYANATE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 34(8), 1995, pp. 652-654
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
34
Issue
8
Year of publication
1995
Pages
652 - 654
Database
ISI
SICI code
0376-4710(1995)34:8<652:SACOSM>2.0.ZU;2-A
Abstract
N,N'-(Ethylene)bis(salicylideneimine) (EDSAL), N,N'-(propylene)bis(sal icyclideneimine) (PDSAL) and N,N'-(o-phenylene)bis(salicyclideneimine) (o-PhenSAL) complexes of Mn(III) selenocyanate and 1,2-dihydro-1,5-di methyl-2-phenyl- 4-(2'-hydroxynaphthylazo-)3H-pyrazol-3-one (NAAP) com plexes of Mn(III) thiocyanate and selenocyanate of the formulae MnL(NC Se) (L = EDSAL, PDSAL or o-PhenSAL) and MnL(NCX)(2) (L = NAAP and X = S or Se) have been isolated and characterized. All the complexes are n on-electrolytic in nature. The IR spectra of these complexes are indic ative of coordination through nitrogen atom of the NCX group.