NOVEL LIGAND TRANSFORMATIONS IN CLUSTER COMPLEXES - ACTIVATION OF C-FBONDS IN A PERFLUOROVINYLDIIRON(I) COMPLEX BY PRIMARY AND SECONDARY-AMINES

Authors
RUMIN R PETILLON FY MANOJLOVICMUIR L MUIR KW YUFIT DS
Citation
R. Rumin et al., NOVEL LIGAND TRANSFORMATIONS IN CLUSTER COMPLEXES - ACTIVATION OF C-FBONDS IN A PERFLUOROVINYLDIIRON(I) COMPLEX BY PRIMARY AND SECONDARY-AMINES, Journal of the Chemical Society, Chemical Communications, (14), 1995, pp. 1431-1432
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
14
Year of publication
1995
Pages
1431 - 1432
Database
ISI
SICI code
0022-4936(1995):14<1431:NLTICC>2.0.ZU;2-G
Abstract
Reactions of primary amines with the perfluorovinyl complex [{Fe(CO)(3 )}(2){mu-C(SMe)(CF3)CCF2}] 1 proceed with cleavage of two C-F bonds to give 2, whereas with secondary amines fluorine migration and C-F bond rupture afford the novel organometallic complex 3; both 2 and 3 have been characterized by X-ray analysis.