XCN (X=CL, BR AND I) - A NOVEL SOURCE OF ISOCYANOGEN

Authors
BLANCH RJ MCCLUSKEY A
Citation
Rj. Blanch et A. Mccluskey, XCN (X=CL, BR AND I) - A NOVEL SOURCE OF ISOCYANOGEN, Chemical physics letters, 241(1-2), 1995, pp. 116-120
Citations number
11
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
241
Issue
1-2
Year of publication
1995
Pages
116 - 120
Database
ISI
SICI code
0009-2614(1995)241:1-2<116:X(BAI->2.0.ZU;2-I
Abstract
Ambient light photolysis of gaseous BrCN, ClCN, and ICN results in the production of isocyanogen (NCNC) as the sole CN containing product. T he flash vacuum pyrolysis of BrCN (1100 degrees C and 10(-5) mbar) gen erates NCNC, NCCN, HOCN, HNCO and the CN radical.