The surface structure, step- and terrace-width distribution of mechano
-chemically prepared, concave-shaped Si(100) substrates, have been det
ermined by scanning tunneling microscopy (STM). The as-prepared surfac
es present a continuous range of local polar miscut angles Theta = 0 d
egrees-12 degrees and the full range of azimuthal directions. Under UH
V treatment the surface breaks up into stepped surfaces with 2 X 1 and
1 X 2 reconstructed terraces. Depending on the local miscut angle The
ta, three topographically different regions can be distinguished. A do
uble-domain structure with single-layer steps is observed for Theta ar
ound 1 degrees. In [001]-like directions scaly arrangements of small t
erraces with both reconstructions were found. In [011]-like directions
and for Theta exceeding 6 degrees, this phase is transformed into a s
ingle-domain structure where terraces are connected by double-layer st
eps. For intermediate Theta, a mixture of SL and DL steps was observed
confirming a gradual and not abrupt transition between these phases.
Well ordered high-index faces like (911) and (711) were observed for T
heta exceeding 9 degrees.