The geometric structure of C-60 monolayers on Au(110) has been investi
gated by scanning tunneling microscopy. C-60 rearranges the (1 $($) ov
er bar$$ 10) rows of surface Au atoms into several unique new reconstr
uction patterns, i.e. (1 X 5), (1 X 6) and stepped (1 X 2). The latter
two reconstructions are merely metastable. The stable (1 X 5) reconst
ruction is characterized by only two adsorption sites, in which each C
-60 molecule has two ridge Au atoms as nearest neighbours. The changes
in the Au reconstruction and the tendency to bind to the most reactiv
e surface atoms indicate strong chemical bonding between the substrate
and C-60.