Magnetization induced optical second harmonic generation (MSHG) in com
bination with the magneto-optical Kerr effect (MOKE) was used to study
thin Co films and Cu/Co multilayers of thicknesses between 1 and 20 m
onolayers (ML) grown on a Cu(001) substrate. From the different depend
ence of MSHG and MOKE on Co film thickness we get direct information a
bout the interface sensitivity of MSHG. Modifying the vacuum/Co interf
ace by gas adsorption yields the relative contributions of the vacuum/
Co and the Co/Cu(001)-substrate interfaces. Both MSHG and MOKE data ca
n be accurately described by a multiple reflection model.