CU-63 AND AG-109 NMR-STUDIES OF COPPER(I) AND SILVER(I) SALTS IN MIXED-SOLVENTS CONTAINING NITRILES

Authors
GILL DS RODEHUSER L RUBINI P DELPUECH JJ
Citation
Ds. Gill et al., CU-63 AND AG-109 NMR-STUDIES OF COPPER(I) AND SILVER(I) SALTS IN MIXED-SOLVENTS CONTAINING NITRILES, Journal of the Chemical Society. Faraday transactions, 91(15), 1995, pp. 2307-2312
Citations number
19
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
91
Issue
15
Year of publication
1995
Pages
2307 - 2312
Database
ISI
SICI code
0956-5000(1995)91:15<2307:CAANOC>2.0.ZU;2-1
Abstract
The solvation of copper(I) in mixed solvent systems containing acetoni trile or benzonitrile and the co-solvents propionitrile, butyronitrile , valeronitrile, as well as trimethyl-, triethyl- and tributyl-phosphi te has been examined by Cu-63 NMR and also, in the case of the phosphi tes, by P-31 NMR. The concentration dependence and the variation of th e chemical shift of the silver-109 signal with solvent composition hav e been studied in solutions of silver trifluoroacetate (AgO2CCF3).