We report an X-ray radial distribution function study of Li2SiS3 glass
done using Mo K-alpha radiation. Si-S and Li-S interactions occur at
2.16 and 2.67 Angstrom respectively. Si is surrounded by four sulfur a
toms. Two Si-Si interactions at 3.7 and 4.26 Angstrom confirm the abse
nce of edge sharing among SiS4 tetrahedra. Li is surrounded by sulphur
atoms at 2.67 Angstrom, with an average coordination number of 5.3. R
esults are compared with those of the molecular dynamics study of the
same glass.