Atoms in very high Rydberg states, 100 less than or similar to n less
than or similar to 1100, are used to investigate electron-molecule int
eractions at electron energies extending down to a few microelectronvo
lts. At such energies the cross section for electron capture by CCl4 i
s observed to vary inversely with electron velocity, indicative of an
s-wave process. Studies with the polar target CH3Cl suggest that dipol
e-supported states may be important in inelastic electron-polar molecu
le scattering at very low electron energies.